Significados de regioselectivity em inglês

The observed reversed regioselectivity can be explained by two mechanisms.

This enables rapid and reliable regioselectivity prediction for radical C-H bond functionalization of heterocycles.

This method displays good regioselectivity and high efficiency.

Here, we describe a regioselectivity indicator diagram based on the time-course of only 2 HPAEC-PAD signals.

Consequently, the diagram should become a valuable tool in the search towards better understanding and engineering of regioselectivity in LPMOs.

They also reassert the operation of general 'working rules' governing conformational change and regioselectivity in both singly and doubly hydrated monosaccharides.

The method shows a good scope with a wide-range of sulfoximine and alkynoates and displays regioselectivity in forming single regioisomers in good yields.

The influence of the substituent on the regioselectivity of the cycloaddition has been examined using several model systems and two methods of nitrone formation.

The synthetic design of this transformation relies heavily on the knowledge of regioselectivity, while a quantified and efficient regioselectivity prediction approach is still elusive.

In agreement with these findings, three out of four positively selected amino acids investigated in previous biochemical studies of CYP3A affect the activity and regioselectivity.

Monosubstituted siliranes underwent insertion into the more substituted Si-C bond of the ring, although this regioselectivity was eroded as substitution increased on the silirane ring.

Control experiments and density functional theory (M06L-SMD) computations also suggest the crucial role of the substrate in controlling the regioselectivity of unsymmetrical 1,3-diynes.

Similar pathways also determine the regioselectivities, that is, whether the more or less substituted C-C bond of cyclopropane is cleaved.

The results corroborate evidence that filamentous fungi have evolved AA9 LPMOs with distinct substrate specificities and regioselectivities, which likely have complementary functions during biomass degradation.

The observed reversed regioselectivity can be explained by two mechanisms.

This enables rapid and reliable regioselectivity prediction for radical C-H bond functionalization of heterocycles.