He already won gold in the 100m earlier in the week, beatingAmerican rival Justin Gatlin.
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Meanwhile Tonga finished third in the Preliminary event after beatingAmerican Samoa 2-0 in the earlier fixture.
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Montgomerie was both relieved and delighted after beatingAmerican Davis Love two up in the 36hole final on the Grayhawk club's Raptor course.
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The New Zealand boxer Joseph Parker has won the World Boxing Organization World Heavyweight title after beatingAmerican-Mexican Andy Ruiz Jr in a majority decision.
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Meanwhile the Cook Islands finished on a winning note, beatingAmerican Samoa 2-1 to give the home fans something to cheer about.
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Padraig Harrington also made it into the next round after beatingAmerican Jeff Maggert 1up, finishing with a birdie at the par five 18th.