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The platinum-rich shell exhibits compressive strain, which results in a shift of the electronicbandstructure of platinum and weakening chemisorption of oxygenated species.
2
The electronicbandstructure suggests that Pnnm-CN is an insulator with an indirect band gap of about 3.7 eV.
3
Here, the electronicbandstructures of CFO and CFO-N were probed using Ultraviolet photoelectron spectroscopy (UPS) and UV-Visible spectroscopy.