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The slope of the BEP relation is strongly coupled to the adsorbate geometry in the transition state.
2
Therefore, the NO adsorbate behaves as a nonvolatile sensor for the detection of locally applied repulsive torque.
3
Here, we present the first infrared spectroscopic evidence for significant polarization effects in the spectroscopic detection of adsorbate vibrational frequencies.
4
The other two, more traditional, approaches give values of the specific surface area that decrease as the length of the adsorbate used increases.
5
Activation of targeted adsorbate-metal bonds through direct photoexcitation of hybridized electronic states enabled selectivity control in preferential CO oxidation in H2 rich streams.
6
Using a Gaussian process regression model, the free energy of all possible adsorbate coverages for surfaces is predicted for a finite number of adsorption sites.
7
An NO-functionalized tip, which was characterized by scanning tunneling microscopy and inelastic electron tunneling spectroscopy, can convert an upright NO adsorbate into a flat-lying NO.
8
Passive samplers demonstrated a linear range and agreement with predictions for adsorbate loadings from approximately 1 ng to nearly 10 microg.
9
Furthermore, the simulated TPD spectra clearly depict the previous experimental results of both adsorbates after considering the diffusion.
10
The new model specifically accounts for sites that are left uncovered in the case of adsorption by linear adsorbates.
11
The direct visualization of the localization of micropollutant adsorbates in activated carbon particles provided direct evidence of shell adsorption.
12
Our results indicate that the diffusion barriers of the adsorbates at high coverage are smaller than their direct desorption energies.
13
Hence, to improve our model, in this study, we considered the diffusion of adsorbates from the sub-monolayer to the second layer.
14
EFM provides a straightforward identification of graphene with different numbers of layers on the substrate where topographical determination is hindered by adsorbates.
15
Our results have important implications for the use of graphene for future device applications that require electronic decoupling between functional molecular adsorbates and substrates.
16
Surface phase diagrams are necessary for understanding surface chemistry in electrochemical catalysis, where a range of adsorbates and coverages exist at varying applied potentials.