The C5-alkene diols were prepared following published synthesis procedures.
2
DFT calculations show that alkene addition is intrinsically more favorable, but that predistortion can lead to C-H insertion.
3
One important class of biological reactive intermediates arising in the course of human xenobiotic metabolism are arene and alkene oxides.
4
This approach provides corroborating evidence for the structures of certain bridgehead alkene natural products while leading to the reassignment of several other structures.
5
The modified peptides contain groups suitable for post-assembly click reactions in water, namely azides and alkenes.
6
Substituted alkenes provided products that contain all carbon or nitrogen bearing quaternary centers in high yield.
7
Of the measured compounds, reactive alkenes and CO showed the strongest potential to form ground-level ozone.
8
The conversions of surface-bound alkyl groups to alkanes and alkenes are important steps in many heterogeneously catalyzed reactions.
9
We also report the experimental studies that extend the substrate scope of alkenes to ethyl vinyl ethers and thioethers.