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These observations were tentatively related to the strength of the metal-carboxylate bond.
2
On the other hand, the carboxylate form of CPT-11 exhibited much less variability.
3
Each anion had a carboxylate group and at least one other polar moiety.
4
Remarkably, both of these challenges were overcome by incorporation of a single carboxylate moiety.
5
Here the organic ligand acts as tetradendate linker via two of the carboxylate groups.
6
Theoretical studies show that the free carboxylate(s) are involved in binding with metals.
7
This implies that the length of the carboxylate side chain is critical for cation selectivity.
8
The carboxylate group of the benzoate moiety must be in ortho position to the amino group.
9
The free carboxylate group(s) in the MOFs inspire us to elaborate their metal capturing properties.
10
Our results indicate that monodentate carboxylate oxygens of both conserved Asp residues bridge the two metal ions.
11
The apoprotein retained delta 1-pyrroline-5-carboxylate dehydrogenase and DNA binding but not proline dehydrogenase activity.
12
The growth rate and 1-aminocyclopropane-1-carboxylate deaminase activity of transformant strains was lower compared to the wild-type.
13
The ATP-dependent uptake of the carboxylate form of SN-38 showed a single saturable component but was detectable only in one human cMV sample.
14
The carboxylate group of propionate bound in the active site makes numerous interactions with active-site residues, defining the substrate binding site of the enzyme.
15
The PutA protein is both the put repressor and a membrane-bound enzyme with proline and delta 1-pyrroline-5-carboxylate dehydrogenase activities.
16
Introduction of two methyl groups strategically at the alpha position to the carboxylate in the linker further improved the rate of cyclization by nearly 2-fold.