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This process provides an alternative approach for protein semisynthesis through the use of recombinant protein hydrazides as thioester surrogates.
2
In future applications this enzyme will be a promising starting point for the development of novel strategies for the semisynthesis of all-L-proteins.
Использование термина total synthesis на английском
1
The development of a stereoselective totalsynthesis of β-dihydroagarofuran 4 is described.
2
Asymmetric totalsynthesis of TAN-1085 via Pd-catalyzed atroposelective C-H olefination is described.
3
The totalsynthesis of the macrocyclic natural product engelhardione is reported.
4
Here, we report a modular totalsynthesis of RIF-1 stereoisomers and structural analogs.
5
Various strategies were conceived, setbacks encountered, and solutions developed, ultimately leading to a successful enantioselective totalsynthesis.
6
The structure and potency of lichostatinal (3) was verified by totalsynthesis and kinetic characterization.
7
The first totalsynthesis of structurally unique flavonoids 1a and 1b is described.
8
While organic synthesis provides access to many natural products, totalsynthesis of numerous complex molecules is not economically feasible.
9
Its structure was identified using nuclear magnetic resonance, mass spectrometry, and molecular modeling experiments, and confirmed by totalsynthesis.
10
Through the Recorder, you are a part of the totalsynthesis, not just the isolated portion in this body.
11
We now report the synthetic studies on this intriguing natural product, leading to the structural revision and the first totalsynthesis.
12
The structure was elucidated on the basis of the analysis of spectroscopic data and confirmed by a simple one-step totalsynthesis.
13
God is not to be conceived as a consciousness enveloping the entire universe, past, present and future, in a totalsynthesis.
14
The synthetic approach might provide a unified strategy for the totalsynthesis of natural products containing trans-9,10-dihydrophenanthrene-9,10-diol motifs.
15
These likewise show a progressive increase in number, but of a much slower rate than that manifested by the totalsynthesis of elements.
16
This signature CD feature suggested the absolute stereochemical relationship between these chromophores as originally assigned and which was later confirmed by stereospecific totalsynthesis.